Na_2.4Al_0.4Mn_2.6O₇ anionic redox cathode material for sodium-ion batteries – a combined experimental and theoretical approach to elucidate its charge storage mechanism

Sodium and sodium-ion energy storage batteries

1359-0286/$ see front matter 2012 Elsevier Ltd. A http://dx.doi.org/10.1016/j.cossms.2012.04.002 ⇑ Corresponding author. E-mail address: [email protected] (L.F. Nazar). Owing to almost unmatched volumetric energy density, Li-ion batteries have dominated the portable electronics industry and solid state electrochemical literature for the past 20 years. Not only will that continue, but they ar...

Na2CoSiO4 as a cathode material for sodium-ion batteries: structure, electrochemistry and diffusion pathways.

The importance of developing new low-cost and safe cathodes for large-scale sodium batteries has led to recent interest in silicate compounds. A novel cobalt orthosilicate, Na2CoSiO4, shows promise as a high voltage (3.3 V vs. Na/Na+) cathode material for sodium-ion batteries. Here, the synthesis and room temperature electrochemical performance of Na2CoSiO4 have been investigated with the compo...

Utilizing Co2+/Co3+ Redox Couple in P2‐Layered Na0.66Co0.22Mn0.44Ti0.34O2 Cathode for Sodium‐Ion Batteries

Developing sodium-ion batteries for large-scale energy storage applications is facing big challenges of the lack of high-performance cathode materials. Here, a series of new cathode materials Na0.66Co x Mn0.66-x Ti0.34O2 for sodium-ion batteries are designed and synthesized aiming to reduce transition metal-ion ordering, charge ordering, as well as Na+ and vacancy ordering. An interesting struc...

C/Li2MnSiO4 Nanocomposite Cathode Material for Li-Ion Batteries

Cathode Material with Superior Rate Capability for Na-Ion Batteries

Dr. L. Liu, Prof. X. Li, Dr. S.-H. Bo, Dr. Y. Wang, Dr. N. Twu, Prof. G. Ceder Department of Materials Science and Engineering Massachusetts Institute of Technology Cambridge , MA 02139 , USA E-mail: [email protected] Prof. X. Li John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge , MA 02138 , USA Prof. H. Chen The Woodruff School of Mechanical Engineering Georg...